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LK-99(LK99) Chemical properties

Chemical Composition of LK-99(LK99)

The chemical composition of LK-99(LK99) approximates to Pb9Cu(PO4)6O. This implies that, in comparison with pure lead-apatite (Pb10(PO4)6O), around one quarter of Pb(II) ions situated at position 2 of the apatite structure are substituted by Cu(II) ions.

Synthesis Method of LK-99(LK99)

Lee et al. devised a method for the chemical synthesis of the LK-99(LK99) material by generating lanarkite from a 1:1 molar mixture of lead(II) oxide (PbO) and lead(II) sulfate (Pb(SO4)) powders, then heating at 725 °C (1,000 K; 1,340 °F) for 24 hours:

PbO + Pb(SO4) → Pb2(SO4)O

Further Processing of Lanarkite

In addition, copper(I) phosphide (Cu3P) is produced by mixing copper (Cu) and phosphorus (P) powders in a 3:1 molar ratio in a sealed tube under vacuum and heated to 550 °C (820 K; 1,000 °F) for 48 hours:

Cu + P → Cu3P

Final Preparation Step of LK-99(LK99)

The lanarkite and copper phosphide crystals are ground into a powder, placed in a sealed tube under vacuum, and heated to 925 °C (1,200 K; 1,700 °F) for between 5‒20 hours, leading to the formation of LK-99(LK99):

Pb2(SO4)O + Cu3P + O2 (g) → Pb10-xCux(PO4)6O + S (g), where (0.9 < x < 1.1)